From One-Photon to Two-Photon Probes: "Caged" Compounds, Actuators, and Photoswitches

被引：214
|
作者：
Bort, Guillaume [1 ]
Gallavardin, Thibault [1 ]
Ogden, David [2 ]
Dalko, Peter I. [1 ]
机构：
[1] Univ Paris 05, CNRS, Lab Chim & Biochim Pharmacol & Toxicol, F-75270 Paris, France
[2] Univ Paris 05, CNRS, Lab Physiol Cerebrale, F-75270 Paris, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 17期
关键词：
caged compounds; cell signaling; photochemistry; protecting groups; signal transduction; PHOTOLABILE PROTECTING GROUPS; UNCAGING CROSS-SECTIONS; HIGHLY EFFICIENT; COOPERATIVE ENHANCEMENT; IMAGING MICROSCOPY; CYCLIC-NUCLEOTIDES; CARBOXYLIC-ACIDS; LASER PHOTOLYSIS; OPTICAL CONTROL; CAGING GROUP;
D O I：
10.1002/anie.201204203
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Molecular systems that can be remotely controlled by light are gaining increasing importance in cell biology, physiology, and neurosciences because of the spatial and temporal precision that is achievable with laser microscopy. Two-photon excitation has significant advantages deep in biological tissues, but raises problems in the design of smart probes compatible with cell physiology. This Review discusses the chemical challenges in generating suitable two-photon probes.
引用
收藏
页码：4526 / 4537
页数：12
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