Orbital-selective single molecule reactions on a metal surface studied using low-temperature scanning tunneling microscopy

被引：6

作者：

Katano, Satoshi ^{[1
,2
]}

Kim, Yousoo ^{[2
]}

Trenary, Michael ^{[3
]}

Kawai, Maki ^{[4
]}

机构：

[1] Tohoku Univ, Elect Commun Res Inst, Sendai, Miyagi 9808577, Japan

[2] RIKEN, Saitama 3510198, Japan

[3] Univ Illinois, Dept Chem, Chicago, IL 60607 USA

[4] Univ Tokyo, Dept Adv Mat Sci, Chiba 2778651, Japan

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 41期

基金：

美国国家科学基金会;

关键词：

VIBRATIONAL-EXCITATION; PLATINUM; 111; ACETONITRILE; MANIPULATION; DESORPTION; PT(111);

D O I：

10.1039/c3cc40949j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The injection of tunneling electrons from the scanning tunneling microscope tip into the molecule induces the single molecule reactions of acetonitrile adsorbed on Pt(111). The voltage dependence indicated that the resonant tunneling of electrons into the antibonding molecular orbitals gives rise to the desorption and the decomposition of acetonitrile.

引用

页码：4679 / 4681

页数：3

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