Ultrathin Porous NiCo2O4 Nanosheet Arrays on Flexible Carbon Fabric for High-Performance Supercapacitors

被引:251
|
作者
Du, Jun [1 ,2 ]
Zhou, Gang [1 ,2 ]
Zhang, Haiming [1 ,2 ]
Cheng, Chao [1 ,2 ]
Ma, Jianmin [1 ,2 ]
Wei, Weifeng [3 ]
Chen, Libao [1 ,2 ]
Wang, Taihong [1 ,2 ]
机构
[1] Hunan Univ, Minist Educ, Key Lab Micronano Optoelect Devices, Changsha 410082, Hunan, Peoples R China
[2] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
[3] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
NiCo2O4; nanosheet arrays; carbon fabric; flexible; supercapacitor; ELECTROCHEMICAL ENERGY-STORAGE; ELECTRODES; COMPOSITES; DEVICES; DESIGN; PAPER;
D O I
10.1021/am4017335
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
NiCo2O4 with higher specific capacitance is an excellent pseudocapacitive material. However, the bulk NiCo2O4 material prevents the achievement of high energy desity and great rate performance due to the limited electroactive surface area. In this work, NiCo2O4 nanosheet arrays were deposited on flexible carbon fabric (CF) as a high-performance electrode for supercapacitors. The NiCo2O4 arrays were constructed by interconnected ultrathin nanosheets (10 nm) with many interparticle pores. The porous feature of NiCo2O4 nanosheets increases the amount of electroactive sites and facilitates the electrolyte penetration. Hence, the NiCo2O4/CF composites exhibited a high specific capacitance of 2658 F g(-1) (2 A g(-1))(,) good rate performance, and superior cycling life, suggesting the NiCo2O4/CF is a promising electrode material for flexible electrochemical capacitors.
引用
收藏
页码:7405 / 7409
页数:5
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