3,4-Bis(5-iodo-2-methylthien-3-yl)-2,5-dihydrothiophene: A powerful synthon for the preparation of photochromic dithienylethene derivatives

被引：0
|
作者：
Nan, X [1 ]
De, XZ [1 ]
Yi, C [1 ]
机构：
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China
来源：
SYNLETT | 2006年 / 05期
关键词：
dithienylethene; photochromism; Suzuki coupling;
D O I：
10.1055/s-2006-933108
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A dithienylethene synthon, 3,4-bis-(5-iodo-2-methylthien-3-yl)-2,5-dihydrothiophene, was prepared and used as a starting material for the preparation of several photochromic dithienylethene derivatives via Suzuki cross-coupling reactions. The dithienylethene synthon was stable once stored in the dark at room temperature.
引用
收藏
页码：737 / 740
页数：4
相关论文
共 50 条
  • [1] Synthesis and photochromic mechanism of 3,4-bis[2,5-dimethylthiophene-3-yl]-2,5-dihydrothiophene
    Xu, BA
    Huang, ZN
    Jin, S
    Ming, YF
    Fan, MG
    Yao, SD
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1997, 110 (01) : 35 - 40
  • [2] Synthesis of photochromic 3,4-bis(1,2-dimethylindol-3-yl)-2,5-dihydrothiophene
    Rybalkin, V. P.
    Shepelenko, E. N.
    Popova, L. L.
    Dubonosov, A. D.
    Metelitsa, A. V.
    Makarova, N. I.
    Bren, V. A.
    Minkin, V. I.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 42 (04) : 619 - 621
  • [3] Synthesis of photochromic 3,4-bis(1,2-dimethylindol-3-yl)-2,5-dihydrothiophene
    V. P. Rybalkin
    E. N. Shepelenko
    L. L. Popova
    A. D. Dubonosov
    A. V. Metelitsa
    N. I. Makarova
    V. A. Bren’
    V. I. Minkin
    Russian Journal of Organic Chemistry, 2006, 42 : 619 - 621
  • [4] REACTIONS OF NUCLEOPHILES WITH 3,4-BIS(BROMOMETHYL)-2,5-DIHYDROTHIOPHENE-1,1-DIOXIDE
    CHOU, TS
    HUNG, SC
    HETEROCYCLES, 1986, 24 (08) : 2303 - 2309
  • [5] Synthesis and Photochromic Property of 1-(Spirobi[fluorene]-2-yl)-3,4-bis(2,5-dimethylfuran-3-yl)-2,5-dihydro-1H-pyrrole
    Li, Caihua
    Zheng, Chunmei
    Zheng, Heping
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2011, 31 (05) : 659 - 664
  • [6] Preparation and reactions of 3,4-bis(tributylstannyl)-2(5H)-furanone
    Mabon, R
    Richecoeur, AME
    Sweeney, JB
    JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (02): : 328 - 329
  • [7] 3,4-bis(1,3-bemzothiazol-2-yl)furan
    MrvosSermek, D
    TralicKulenovic, V
    Nagl, A
    FiserJakic, L
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 2541 - 2543
  • [8] [6,6-DI(5-METHYLTHIOPHEN-2-YL)-2,5-DIMETHYLENE-2,5-DIHYDROTHIOPHENE] DIYLIUM DERIVATIVES - STABLE TRIMETHYLENEMETHANE DICATIONS EXTENDED WITH THIOPHENES
    KAWASE, T
    WEI, CX
    UENO, N
    ODA, M
    CHEMISTRY LETTERS, 1994, (10) : 1901 - 1904
  • [9] Synthesis and characterization of 3,4-bis(pyrazine-2'-yl) furoxan
    Li, Ya-Nan
    Zhang, Zhi-Zhong
    Zhou, Yan-Shui
    Chen, Bin
    Wang, Bo-Zhou
    Huozhayao Xuebao/Chinese Journal of Explosives and Propellants, 2009, 32 (06): : 40 - 43
  • [10] PREPARATION OF FURANORADIALENE BY THE FLASH VACUUM PYROLYSIS OF DIESTERS OF 3,4-BIS(HYDROXYMETHYL)-2,5-DIMETHYLFURAN
    TRAHANOVSKY, WS
    CASSADY, TJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (26) : 8197 - 8201
12345