Synthesis and Evaluation of Changes Induced by Solvent and Substituent in Electronic Absorption Spectra of New Azo Disperse Dyes Containig Barbiturate Ring

被引:6
|
作者
Hamidian, Hooshang [1 ]
Zahedian, Najmeh [2 ]
Ghazanfari, Dadkhoda [2 ]
Fozooni, Samieh [3 ]
机构
[1] PNU, Dept Chem, Tehran 193954697, Iran
[2] Azad Univ, Dept Chem, Kerman, Iran
[3] Shahid Bahonar Univ, Zarand High Educ Ctr, Min Engn Dept, Kerman, Iran
关键词
ACID; COMPLEXES; COPPER; NICKEL; COBALT;
D O I
10.1155/2013/276413
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Six azo disperse dyes were prepared by diazotizing 4-amino hippuric acid and coupled with barbituric acid and 2-thiobarbituric acid. Then, the products were reacted with aromatic aldehyde, sodium acetate, and acetic anhydride, and oxazolone derivatives were formed. Characterization of the dyes was carried out by using UV-Vis, FT-IR, H-1 NMR and C-13 NMR, and mass spectroscopic techniques. The solvatochromic behavior of azo disperse dyes was evaluated in various solvents. The effects of substituents of aromatic aldehyde, barbiturate, and thiobarbiturate ring on the color of dyes were investigated.
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页数:6
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