Synthesis and Characterization of a Dansyl-Based Fluorescent Probe

被引：2

作者：

Zhang Yong ^{[1
]}

Wang Ji-Meng ^{[1
]}

Shu Wei-Hu ^{[1
]}

Chen Qi ^{[1
]}

Ma Zhi-Guang ^{[1
]}

Chen Xue-Mei ^{[1
]}

机构：

[1] Hubei Polytech Univ, Sch Chem & Mat Engn, Huangshi 435003, Hubei, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 29卷 / 01期

关键词：

iron; crystal structure; dansyl; fluorescent probe; COMPLEXES; SENSORS;

D O I：

10.3969/j.issn.1001-4861.2013.00.040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new fluorescent probe bearing dansyl fluorophore was synthesized and characterized in this paper, and its response towards metal ions was examined by fluorescence spectroscopy. The crystal structure of the perchlorate salt of probe showed that N(4) of the benzimidazole ring was found to be protonized. The experimental results showed that the sensor exhibited good selectivity for Fe3+, forming a 1:1 stoichiometric complexation species with Fe3+. CCDC: 867156.

引用

页码：150 / 154

页数：5

共 13 条

[1] Synthesis, structure, and reactivity of model complexes of copper nitrite reductase
Casella, L
Carugo, O
Gullotti, M
Doldi, S
Frassoni, M
[J]. INORGANIC CHEMISTRY, 1996, 35 (05) : 1101 - 1113
[2] Signaling recognition events with fluorescent sensors and switches
de Silva, AP
Gunaratne, HQN
Gunnlaugsson, T
Huxley, AJM
McCoy, CP
Rademacher, JT
Rice, TE
[J]. CHEMICAL REVIEWS, 1997, 97 (05) : 1515 - 1566
[3] Utility and synthetic uses of Mannich reaction: An efficient route for synthesis of thiadiazino-[1,3,5][3,2-a]benzimidazoles
El-Wareth, A
Sarhan, AO
Abdel-Hafez, SH
El-Sherief, H
Aboel-Fadl, T
[J]. SYNTHETIC COMMUNICATIONS, 2006, 36 (08) : 987 - 996
[4] Fe3+-selective fluorescent probe based on rhodamine B and its application in bioimaging
Hu, Zhi-Qiang
Feng, Yong-Cheng
Huang, He-Qing
Ding, Lei
Wang, Xiao-Ming
Lin, Cun-Sheng
Li, Ming
Ma, Cui-Ping
[J]. SENSORS AND ACTUATORS B-CHEMICAL, 2011, 156 (01): : 428 - 432
[5] Fluorescent sensing and selective Pb(II) extraction by a dansylamide ion-exchanger
Kavallieratos, K
Rosenberg, JM
Chen, WZ
Ren, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (18) : 6514 - 6515
[6] Fluorescent nitric oxide detection by copper complexes bearing anthracenyl and dansyl fluorophore ligands
Lim, Mi Hee
Lippard, Stephen J.
[J]. INORGANIC CHEMISTRY, 2006, 45 (22) : 8980 - 8989
[7] Design, synthesis, physicochemical properties, and evaluation of novel iron chelators with fluorescent sensors
Ma, YM
Luo, W
Quinn, PJ
Liu, ZD
Hider, RC
[J]. JOURNAL OF MEDICINAL CHEMISTRY, 2004, 47 (25) : 6349 - 6362
[8] Synthesis of 5-dialkyl(aryl)aminomethyl-8-hydroxyquinoline dansylates as selective fluorescent sensors for Fe3+
Peng, Ruogu
Wang, Feng
Sha, Yaowu
[J]. MOLECULES, 2007, 12 (05) : 1191 - 1201
[9] Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S2053273314026370, 10.1107/S0108767307043930]
[10] Fluorescently-labeled ferrichrome analogs as probes for receptor-mediated, microbial iron uptake
Weizman, H
Ardon, O
Mester, B
Libman, J
Dwir, O
Hadar, Y
Chen, Y
Shanzer, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (49) : 12368 - 12375

← 1 2 →