Carbonylation of amines with a tungsten(IV) carbonyl complex

被引：45
|
作者：
McCusker, JE [1 ]
Abboud, KA [1 ]
McElweeWhite, L [1 ]
机构：
[1] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611
来源：
ORGANOMETALLICS | 1997年 / 16卷 / 17期
关键词：
D O I：
10.1021/om970388f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of [(CO)(2)W(NPh)I-2](2) (1) with 2 equiv of piperidine yielded (CO)(2)W(NPh)I-2(pip). In the presence of excess amine, secondary amines (R2NH) were carbonylated to the formamides R2NCHO while primary amines (R'NH2) were converted to the ureas R'NH-CONHR'.
引用
收藏
页码：3863 / 3866
页数：4
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