Intramolecular aromatic 1,5-hydrogen transfer in free radical reactions. II. Rearrangement of iodobenzophenones.

被引：11

作者：

Cummins, JM ^{[1
]}

Dolling, UH ^{[1
]}

Douglas, AW ^{[1
]}

Karady, S ^{[1
]}

Leonard, WR ^{[1
]}

Marcune, BF ^{[1
]}

机构：

[1] Merck & Co Inc, Merck Res Labs, Dept Proc Res, Rahway, NJ 07065 USA

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 34期

关键词：

radicals and radical reactions; rearrangements; photochemistry;

D O I：

10.1016/S0040-4039(99)01292-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Products derived from the homolysis of the aromatic C-I bond of ortho-iodobenzophenones by photolysis or tributyltin radicals indicate 1,5-hydrogen migration. The reactions include iodine migration, hydrogen abstraction and arylation. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：6153 / 6156

页数：4

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