Zirconium-catalyzed enantioselective carboalumination of "unactivated" alkenes as a new synthetic tool for asymmetric carbon-carbon bond formation

被引：8
|
作者：
Negishi, E [1 ]
Huo, SQ [1 ]
机构：
[1] Purdue Univ, HC Brown & RB Wetherill Labs Chem, W Lafayette, IN 47907 USA
来源：
PURE AND APPLIED CHEMISTRY | 2002年 / 74卷 / 01期
关键词：
D O I：
10.1351/pac200274010151
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The discovery, methodological developments, including those for separation-purification of chiral flexible primary alcohols, and their applications to the syntheses of some natural products of the titled reaction are discussed.
引用
收藏
页码：151 / 157
页数：7
相关论文
共 50 条
  • [1] Zirconium-Catalyzed Asymmetric Carboalumination of Unactivated Terminal Alkenes
    Xu, Shiqing
    Negishi, Ei-ichi
    ACCOUNTS OF CHEMICAL RESEARCH, 2016, 49 (10) : 2158 - 2168
  • [2] Recent advances in zirconium-catalyzed asymmetric carboalumination ("zaca" reaction). Efficient protocols for catalytic asymmetric carbon-carbon bond formation.
    Negishi, E
    Tan, Z
    Liang, B
    Novak, T
    Brown, HC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U329 - U329
  • [3] ZIRCONIUM-CATALYZED HIGHLY REGIOSELECTIVE CARBON-CARBON BOND FORMATION REACTIONS
    SUZUKI, N
    KONDAKOV, DY
    TAKAHASHI, T
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (18) : 8485 - 8486
  • [4] Zirconium-catalyzed asymmetric carboalumination of alkenes: ZACA-lipase-catalyzed acetylation synergy
    Huang, Zhihong
    Tan, Ze
    Novak, Tibor
    Zhu, Gangguo
    Negishi, Ei-ichi
    ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (4-5) : 539 - 545
  • [5] ZIRCONIUM-CATALYZED ETHYLMAGNESATION OF HYDROXYLATED TERMINAL ALKENES - A CATALYTIC AND DIASTEREOSELECTIVE CARBON-CARBON BOND-FORMING REACTION
    HOURI, AF
    DIDIUK, MT
    XU, ZM
    HORAN, NR
    HOVEYDA, AH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (15) : 6614 - 6624
  • [6] SYNTHESES OF CHIRAL HETEROCYCLIC COMPOUNDS VIA ZIRCONIUM-CATALYZED ASYMMETRIC CARBOALUMINATION OF ALKENES (ZACA REACTION)
    Xu, Shiqing
    Negishi, Ei-ichi
    HETEROCYCLES, 2014, 88 (02) : 845 - 877
  • [7] Catalytic asymmetric carbon-carbon bond formation using alkenes as alkylmetal equivalents
    Maksymowicz, Rebecca M.
    Roth, Philippe M. C.
    Fletcher, Stephen P.
    NATURE CHEMISTRY, 2012, 4 (08) : 649 - 654
  • [8] Asymmetric Synthesis of Chiral Cyclopentanes Bearing an All-Carbon Quaternary Stereocenter by Zirconium-Catalyzed Double Carboalumination
    Xu, Shiqing
    Wang, Chuan
    Komiyama, Masato
    Tomonari, Yasuhiko
    Negishi, El-ichi
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (38) : 11502 - 11505
  • [9] Stereoselective formation of carbon-carbon bonds through metal catalysis. The zirconium-catalyzed ethylmagnesation reaction
    1600, (113):
  • [10] New synthetic methodologies for carbon-carbon multiple bond formation
    Shen, YC
    ACTA CHIMICA SINICA, 2000, 58 (03) : 253 - 261
12345