A dual-responsive cross-linked supramolecular polymer network gel: hierarchical supramolecular self-assembly driven by pillararene-based molecular recognition and metal-ligand interactions

被引:41
|
作者
Shao, Li [1 ]
Yang, Jie [1 ]
Hua, Bin [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
关键词
HOST-GUEST INTERACTIONS; SIDE-CHAIN POLYMERS; TWEEZER/GUEST COMPLEXATION; ION COORDINATION; CROWN-ETHER; BOND; PERSPECTIVES; CHEMISTRY; ACID;
D O I
10.1039/c8py00057c
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A novel 2,2-bipyridine-bridged pillar[5]arene dimer was successfully synthesized and further applied for constructing linear supramolecular polymers through pillar[5]arene-based host-guest interactions. Specifically, upon addition of Zn2+ ions, the linear supramolecular polymer could be cross-linked through metal-ligand interactions, resulting in the formation of a novel supramolecular polymer network gel.
引用
收藏
页码:1293 / 1297
页数:5
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