High-performance polythiophene thin-film transistors with nematic liquid crystal modification

The influence of nematic liquid crystal molecules on the electrical properties and microstructure of polymer semiconductors poly(3-hexylthiophene) (P3HT) was investigated. It was found that the introduction of nematic liquid crystal molecules can significantly improve the performance of P3HT thin-film transistors, providing better electrical characteristics and enhanced mobility. The field-effect mobility of the device with liquid crystal modification can be enhanced by up to a factor of ten with respect to that of the pure P3HT device. UV-visible absorption spectroscopy, X-ray diffraction, and atomic force microscopy measurements show that the enhancement of charge-carrier mobility is achieved through a more highly organized morphology and a reduction in the density of traps presents in the P3HT/liquid crystal structure. The results shown here therefore illustrate a high-performance solution-processable thin-film transistors, which is quite feasible and can pave a key step for the practical applications of organic electronic devices. (C) 2012 Elsevier By. All rights reserved.