Polyethyleneimine-functionalized graphene and its layer-by-layer assembly with Prussian blue

被引：63
|
作者：
Shan, Changsheng [1 ]
Wang, Lingnan [1 ]
Han, Dongxue [1 ]
Li, Fenghua [1 ]
Zhang, Qixian [1 ]
Zhang, Xindong [2 ]
Niu, Li [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
[2] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
来源：
THIN SOLID FILMS | 2013年 / 534卷
关键词：
Polyethyleneimine; Graphene; Prussian blue; Layer-by-layer complexation; Electrocatalysis; AQUEOUS DISPERSIONS; GRAPHITE OXIDE; THIN-FILMS; CARBON; ELECTROCHROMISM; NANOPLATELETS; ELECTRODES; REDUCTION; OXIDATION; SENSORS;
D O I：
10.1016/j.tsf.2013.02.011
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The polyethyleneimine (PEI)-functionalized graphene, which showed excellent dispersibility in water, has been simply synthesized in an alkaline solution. The graphene sheets played an important role as connector to assemble the active amino groups in PEI. This composite provided a positive environment for further functionalization. As an example, a [Prussian blue (PB)/PEI-graphene](n) multilayer film has been constructed through layer-by-layer complexation method. The resulting [PB/PEI-graphene](n) multilayer film demonstrated preferable electrochromic property and excellent electrocatalysis towards H2O2, which showed promising potential application in electrochemical sensing. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：572 / 576
页数：5
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