Bis[2-(phenylsulfanyl)benzenethiolato]palladium(II)

被引:2
|
作者
Shimizu, D [1 ]
Takeda, N [1 ]
Sasamori, T [1 ]
Tokitoh, N [1 ]
机构
[1] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan
关键词
D O I
10.1107/S1600536805041711
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [Pd(C12H9S2)(2)], the central Pd atom has a slightly distorted cis-planar four-coordinate geometry defined by the two thiolate and the two sulfanyl S atoms from two 2-(phenylsulfanyl) benzenethiolate ligands. The two phenyl groups are on the same side of the PdS4 plane and indicative of the typical arrangement of intermolecular pi-stacking. Moreover, an intermolecular C-H center dot center dot center dot pi stacking interaction links molecules to one another.
引用
收藏
页码:M166 / M167
页数:2
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