Visualization of synthetic helical polymers by high-resolution atomic force microscopy

被引：121

作者：

Kumaki, Jiro ^{[1
]}

Sakurai, Shin-ichiro ^{[1
]}

Yashima, Eiji ^{[1
,2
]}

机构：

[1] Japan Sci & Technol Agcy, ERATO, Yashima Super Struct Helix Project, Tokyo, Japan

[2] Nagoya Univ, Grad Sch Engn, Dept Mol Design & Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 03期

基金：

日本学术振兴会; 日本科学技术振兴机构;

关键词：

SYNDIOTACTIC POLY(METHYL METHACRYLATE); MACROMOLECULAR HELICITY; POLY(PHENYLACETYLENE); AMPLIFICATION; CHIRALITY; POLYACETYLENE; STEREOCOMPLEX; FULLERENES; COMPLEXES; PENDANTS;

D O I：

10.1039/b718433f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct observations of the helical structures of artificial helical polymers, such as helical polyacetylenes and polyisocyanides, by atomic force microscopy (AFM) are described in this tutorial review. The two-dimensional helix bundle formation of specific helical polymers on substrates under solvent vapor exposure permits us to determine their helical structures, including their helical pitch and handedness, at a molecular level by AFM in the tapping mode. The direct observation of supramolecular helical structures based on stereoregular poly(methyl methacrylate)s is also described.

引用

页码：737 / 746

页数：10

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