Nucleation rates of methane hydrate from water in oil emulsions

被引：41
|
作者：
Stoporev, Andrey S. [1 ]
Manakov, Andrey Yu. [1 ,2 ]
Altunina, Lubov' K. [3 ]
Strelets, Larisa A. [3 ]
Kosyakov, Viktor I. [1 ]
机构：
[1] SB RAS, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
[3] Inst Petr Chem, Tomsk 634021, Russia
来源：
CANADIAN JOURNAL OF CHEMISTRY | 2015年 / 93卷 / 08期
关键词：
methane hydrate; nucleation rate; induction time; crude oil; emulsion; HETEROGENEOUS NUCLEATION; INDUCTION TIME; GAS; KINETICS; CARBON; DSC; STABILITY; CHEMISTRY; MODEL; FLOW;
D O I：
10.1139/cjc-2014-0507
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Nucleation of methane hydrate from water emulsions in five different kinds of crude oil and in decane have been studied with the use of isothermal methods. The experiments were conducted at a temperature of -5 degrees C and pressure of 12 MPa. It is shown that the nucleation rates tend to decrease with the increase in the density of the organic liquid used to make the emulsion. It is most likely that the observed regularities are related to the rate of methane diffusion to water surface.
引用
收藏
页码：882 / 887
页数：6
相关论文
共 50 条
  • [1] Nucleation of Methane Hydrate in Water-In-Oil Emulsions: Role of the Phase Boundary
    Stoporev, Andrey S.
    Manakov, Andrey Yu.
    Kosyakov, Viktor I.
    Shestakov, Vladimir A.
    Altunina, Lubov' K.
    Strelets, Larisa A.
    ENERGY & FUELS, 2016, 30 (05) : 3735 - 3741
  • [2] Effect of reactor wall material on the nucleation of methane hydrate in water-in-oil emulsions
    Stoporev, Andrey S.
    Svarovskaya, Lidiya I.
    Strelets, Larisa A.
    Altunina, Lyubov K.
    Manakov, Andrey Yu.
    MENDELEEV COMMUNICATIONS, 2018, 28 (03) : 343 - 344
  • [3] Nucleation of methane hydrate and ice in the emulsions of water in five kinds of crude oils
    Shestakov, V. A.
    Kosyakov, V. I.
    Manakov, A. Yu.
    Stoporev, A. S.
    Grachev, E. V.
    PETROLEUM SCIENCE AND TECHNOLOGY, 2019, 37 (05) : 513 - 518
  • [4] Effect of the Degree of Oil Biodegradation on the Crystallization of Methane Hydrate and Ice in Water-Oil Emulsions
    Stoporev, A. S.
    Svarovskaya, L. I.
    Semenov, A. P.
    Strelets, L. A.
    Altunina, L. K.
    Manakov, A. Yu.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2019, 92 (02) : 254 - 261
  • [5] Effect of the Degree of Oil Biodegradation on the Crystallization of Methane Hydrate and Ice in Water-Oil Emulsions
    Stoporev, A.S.
    Svarovskaya, L.I.
    Semenov, A.P.
    Strelets, L.A.
    Altunina, L.K.
    Manakov, A. Yu.
    Russian Journal of Applied Chemistry, 2019, 92 (02): : 254 - 261
  • [6] Effect of the Degree of Oil Biodegradation on the Crystallization of Methane Hydrate and Ice in Water-Oil Emulsions
    A. S. Stoporev
    L. I. Svarovskaya
    A. P. Semenov
    L. A. Strelets
    L. K. Altunina
    A. Yu. Manakov
    Russian Journal of Applied Chemistry, 2019, 92 : 254 - 261
  • [7] Unusual examples of methane hydrate nucleation in bilayer water-oil systems
    Manakov, Andrey Yu.
    Adamova, Tatyana P.
    Stoporev, Andrey S.
    MENDELEEV COMMUNICATIONS, 2018, 28 (06) : 663 - 665
  • [8] Methane recovery from coal mine gas using hydrate formation in water-in-oil emulsions
    Zhong, Dong-Liang
    Ding, Kun
    Lu, Yi-Yu
    Yan, Jin
    Zhao, Wei-Long
    APPLIED ENERGY, 2016, 162 : 1619 - 1626
  • [9] Experimental study of methane hydrate formation and agglomeration in waxy oil-in-water emulsions
    Wang, Lin
    Chen, Jiaxin
    Ma, Tingxia
    Jing, Jiaqiang
    Lei, Lijun
    Guo, Junyu
    ENERGY, 2024, 288
  • [10] Nuclear Magnetic Resonance Analysis of Methane Hydrate Formation in Water-in-Oil Emulsions
    Aichele, Clint P.
    Chapman, Walter G.
    Rhyne, Lee D.
    Subramani, Hariprasad J.
    Montesi, Alberto
    Creek, Jefferson L.
    House, Waylon
    ENERGY & FUELS, 2009, 23 (1-2) : 835 - 841
12345