Modelling of pyrolysis of coal-biomass blends using thermogravimetric analysis

被引:124
|
作者
Sadhukhan, Anup Kumar [1 ]
Gupta, Parthapratim [1 ]
Goyal, Tripurari [2 ]
Saha, Ranajit Kumar [2 ]
机构
[1] Natl Inst Technol, Dept Chem Engn, Durgapur 713209, W Bengal, India
[2] Indian Inst Technol, Dept Chem Engn, Kharagpur 721302, W Bengal, India
关键词
co-pyrolysis; biomass; kinetic model; synergistic effect;
D O I
10.1016/j.biortech.2008.03.047
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The primary objective of this work was to develop an appropriate model to explain the co-pyrolysis behaviour of lignite coal-biomass blends with different proportions using a thermogravimetric analyzer. A new parallel-series kinetic model was proposed to predict the pyrolysis behaviour of biomass over the entire pyrolysis regime, while a kinetic model similar to that of Anthony and Howard [Anthony, D.B., Howard, J.B., 1976. Coal devolatilization and hydrogasification. AIChE Journal 22(4), 625-656] was used for pyrolysis of coal. Analysis of mass loss history of blends showed an absence of synergistic effect between coal and biomass. Co-pyrolysis mass-loss profiles of the blends were predicted using the estimated kinetic parameters of coal and biomass. Excellent agreement was found between the predicted and the experimental results. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:8022 / 8026
页数:5
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