Polyoxometalate salts of cationic nitronyl nitroxide free radicals

被引：3
|
作者：
Coronado, Eugenio [1 ]
Gimenez-Saiz, Carlos [1 ]
Gomez-Garcia, Carlos J. [1 ]
Romero, Francisco M. [1 ]
机构：
[1] Univ Valencia, Inst Ciencia Mol, E-46980 Paterna, Spain
来源：
SOLID STATE SCIENCES | 2008年 / 10卷 / 12期
关键词：
Nitroxide radicals; Polyoxometalates; Magnetism;
D O I：
10.1016/j.solidstatesciences.2008.01.031
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The cationic nitronyl nitroxide free radical of the N-methylpyridinium type p-MepyNN(+) has been combined with [Mo8O26](4-) and Keggin [SiW12O40](4-) polyanions to afford salts (p-MepyNN)(4)[Mo8O26]center dot(DMSO = (DMSO = dimethylsulfoxide) (1) and (p-MepyNN)(4)[SiW12O40]center dot 6DMF (DMF = dimethylformamide) (2). Herein, their structural and magnetic properties are described.
引用
收藏
页码：1794 / 1799
页数：6
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