Glycidyl Azide Polymer (GAP). II. Reaction Mechanism

被引：5

作者：

Ribeiro, Sandro P. ^{[1
]}

Santiago, David G. ^{[1
]}

Vianna, Ardson dos S., Jr. ^{[1
]}

机构：

[1] Univ Sao Paulo, Escola Politecn, Dept Engn Quim, BR-05508010 Sao Paulo, Brazil

来源：

POLIMEROS-CIENCIA E TECNOLOGIA | 2012年 / 22卷 / 05期

关键词：

Syntheses; GAP; elementary reactions; reaction mechanism; energetic compound; POLYEPICHLOROHYDRIN; ADDITIVES;

D O I：

10.1590/S0104-14282012005000043

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

GAP is an energetic material that can be used as binder or plasticizing agent in propellants and explosive mixtures. The glycidyl azide polymer (GAP) can be synthesized by direct conversion of epichlorohydrin. Here, a mechanism is proposed for the reaction used, based on an analysis of infrared spectra of intermediate species.

引用

页码：414 / 421

页数：8

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