Low-temperature synthesis of ZnO nanorods using organic-inorganic composite as a seed layer

被引:5
|
作者
Ueno, Naoyuki [1 ]
Nakanishi, Kouji [2 ]
Ohta, Toshiaki [2 ]
Egashira, Yasuyuki [1 ]
Nishiyama, Norikazu [1 ]
机构
[1] Osaka Univ, Grad Sch Engn Sci, Div Chem Engn, Toyonaka, Osaka 5608531, Japan
[2] Ritsumeikan Univ, SR Ctr, Shiga 5258577, Japan
关键词
Nanostructures; Semiconductors; Chemical synthesis; X-ray absorption fine structure; Zinc oxide; P-TYPE ZNO; MOLECULAR-BEAM EPITAXY; THIN-FILMS; HYDROTHERMAL GROWTH; MORPHOLOGY CONTROL; FABRICATION; DEPOSITION; ARRAYS; ROUTE;
D O I
10.1016/j.tsf.2012.02.054
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Well-aligned zinc oxide (ZnO) nanorods were synthesized using a low-temperature hydrothermal method employing a zinc/sodium dodecyl sulfate (Zn/SDS) composite as a seed layer. The results of X-ray diffraction measurements indicate that the Zn/SDS composite has a lamellar structure with an interlayer distance of 3.12 nm, which is shorter than that of the lamellar structure of SDS (3.82 nm) due to ion exchange between Zn and Na. The results of X-ray absorption fine structure analyses suggest that ZnO crystals start to grow after an induction period of 20-30 min. The length of nanorods and the aspect ratio of ZnO nanorods could be controlled by altering the molarity of ammonium and zinc nitrate in the growth solutions. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:4291 / 4296
页数:6
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