Synthesis and complex-forming properties of N-substituted diazacrown ethers

被引：2
|
作者：
Luk'yanenko, NG [1 ]
Basok, SS [1 ]
Kulygina, EY [1 ]
Vetrogon, VI [1 ]
机构：
[1] Natl Acad Sci Ukraine, Bogatskii Phys Chem Inst, Odessa, Ukraine
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2003年 / 73卷 / 12期
关键词：
D O I：
10.1023/B:RUGC.0000025154.24958.66
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
N-Substituted mono- and diazacrown ether with ethoxycarbonylmethyl, 7-phenyl-3,6-dioxaheptyl, p-methoxy, and p-nitrobenzyl groups in the side chain have been synthesized. Their reactions with alkali and alkaline-earth metals have been studied. Substituents affect the complex-forming ability of the "base" macrocycle by changing the basicity of the nitrogen atoms and coordinating with the complexing ion.
引用
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页码：1919 / 1924
页数：6
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