Synthesis of SiC by silicon and carbon combustion in air

被引:53
|
作者
Yang, Yun [1 ,2 ]
Lin, Zhi-Ming [1 ]
Li, Jiang-Tao [1 ]
机构
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
Combustion synthesis in air; Milling; Powders solid state reaction; SiC; Traditional ceramics; TEMPERATURE PROFILE ANALYSIS; POWDER;
D O I
10.1016/j.jeurceramsoc.2008.06.013
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Nano-sized beta-silicon carbide (beta-SiC) powder was successfully prepared using the combustion synthesis method in air in combination with a controlled pre-reaction mechanical activation treatment. For the low-exothermic reaction system Si/C, the effect of the mechanical activation time, one crucial processing variable, on the combustion behavior of Si-C reactant in air was investigated, and the reaction kinetics parameters were measured and calculated to analyze the reaction mechanism of this combustion reaction. Meanwhile, the reaction mechanism was further approved by the thermodynamic calculation. (c) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:175 / 180
页数:6
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