Magnetic and electrical properties of p-type Mn-doped CuCrO2 semiconductors

被引:40
|
作者
Li, Da [1 ]
Fang, Xiaodong [1 ]
Dong, Weiwei [1 ]
Deng, Zanhong [1 ]
Tao, Ruhua [1 ]
Zhou, Shu [1 ]
Wang, Jinmei [1 ]
Wang, Tao [1 ]
Zhao, Yiping [1 ]
Zhu, Xuebin [2 ]
机构
[1] Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Key Lab New Thin Film Solar Cells, Hefei 230031, Peoples R China
[2] Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China
关键词
MAGNETOTRANSPORT PROPERTIES; THIN-FILMS; FERROMAGNETISM; SUBSTITUTION; CUALO2; CR;
D O I
10.1088/0022-3727/42/5/055009
中图分类号
O59 [应用物理学];
学科分类号
摘要
Mn-doped CuCrO2 polycrystalline semiconductors were synthesized by the sol-gel method. The valence state of the Mn ions in the CuCr1-xMnxO2 samples was identified as 3+ by analysing their lattice parameters, their electrical properties and their x-ray photoelectron spectra. The temperature dependence of the susceptibility of all samples exhibits paramagnetic behaviour at high temperature. For x = 0.20 the samples exhibit a clear ferromagnetic ( FM) transition at 120 K. Clear hysteresis loops indicate that FM order exists in the Mn-doped samples at 50 K. All samples behave like semiconductors. The electrical and magnetic properties indicate that the ferromagnetism can be attributed to the double exchange interaction between the Mn3+ and Cr3+ in CuCr1-xMnxO2 semiconductors.
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页数:6
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