Microwave-assisted amination from aryl triflates without base and catalyst

被引：61
|
作者：
Xu, G [1 ]
Wang, YG [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
来源：
ORGANIC LETTERS | 2004年 / 6卷 / 06期
关键词：
D O I：
10.1021/ol049963j
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] Aryl triflates are effectively converted to the corresponding anilines under microwave irradiation in 1 -methyl-2-pyridone (NMP) without base and catalyst. Aryl triflates substituted with both electron-poor and electron-rich groups give good to excellent yields. It is noteworthy that the halogenated aryl triflates can chemoselectively react with amines to afford halogenated anilines.
引用
收藏
页码：985 / 987
页数：3
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