Recent developments in asymmetric catalysis

被引：0

作者：

Pfaltz, A ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

CHIMIA | 2001年 / 55卷 / 09期

关键词：

allylic substitution; asymmetric catalysis; chiral ligands; enantioselective hydrogenation;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric catalysis has long been dominated by C-2-Symmetric bidentate ligands. More recently, sterically and electronically unsymmetrical ligands have found increasing attention. An important family of these are the phosphinooxazoline (PHOX) ligands incorporating one P-coordinating and one N-coordinating unit. Important applications of PHOX ligands include Pd-catalyzed allylic substitution and Ir-catalyzed hydrogenation.

引用

页码：708 / 714

页数：7

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