Solvothermal synthesis and crystal structure of a mixed tri- and dimethyltin coordination polymer, {[(Me3Sn)([μ2-OH)][Me2Sn-μ3-SCH2CO2)]}n

被引：11

作者：

Zhang, RF

Zhang, QF

Shi, Y

Ma, CL ^{[1
]}

机构：

[1] Liaocheng Univ, Dept Chem, Shandong 252059, Peoples R China

[2] Taishan Univ, Tai An 271021, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 08期

基金：

中国国家自然科学基金;

关键词：

organotin; mercaptoacetic acid; coordination polymer; solvothermal synthesis;

D O I：

10.1016/j.jorganchem.2005.11.044

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mixed tri- and dimethyltin coordination polymer, {[(Me3Sn)(mu(2)-OH)][Me2Sn(mu(3)-SCH2CO2)]} (1), has been solvothermally synthesized and structurally characterized by elemental analysis, FT-IR, NMR (H-1, C-13, Sn-119) spectra and X-ray crystallography. This complex displays a I D helical chain structure, in which it can be considered as the tri- and dimethyltin moieties are linked together by the alternate mu(2)-OH groups and [mu(3)-SCH2CO2](2-) units along the [10 (1) over bar] direction. Furthermore, these helical chains are linked together through inter-helix O-H center dot center dot center dot S H-bonding interactions to form a 2D corrugated sheet. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1668 / 1672

页数：5

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