The synthesis of polyoxometalate-based metal-organic frameworks under ionothermal conditions

被引：6
|
作者：
Gan, Xiong [1 ]
Hu, Xiaoxi [1 ]
Shi, Zhongfeng [1 ]
Yin, Yanzhen [1 ]
机构：
[1] Qinzhou Univ, Coll Chem & Chem Engn, Qinzhou, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 16期
基金：
中国国家自然科学基金;
关键词：
Ionothermal; Polyoxometalate-based frameworks; Topology; Electrochemistry; Electrocatalysis; Photocatalysis; IONIC LIQUID; COORDINATION; ELECTRODE; BEHAVIOR; NETWORK;
D O I：
10.1080/00958972.2013.817570
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Using ionic liquid (IL) [Bmim]Br (Bmim=1-butyl-3-methylimidazolium) as solvent has resulted in a polyoxometalate-based metal-organic framework (PMOFs), [Cu(I)Bbi](4)SiW12O40H2O (1) [Bbi=1,1-(1,4-butanediyl)-bis(imidazole)], and was produced via an ionothermal route. Its structure was determined by single-crystal X-ray diffraction. Compound 1 is a 1-D ladder with large voids, resulting in a 3-D supermolecular structure using the classic Keggin-type anion as a second building block. This means utilizing ILs to construct 3-D PMOFs can be efficiently realized. Additionally, electrochemical, electrocatalytic, and photocatalytic properties of 1 were studied.
引用
收藏
页码：2930 / 2939
页数：10
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