meta-Bridged calix[4] arenes: a straightforward synthesis via organomercurial chemistry

被引：28
|
作者：
Flidrova, Karolina [1 ]
Slavik, Petr [1 ]
Eigner, Vaclav
Dvorakova, Hana
Lhotak, Pavel [1 ]
机构：
[1] Prague Inst Chem Technol, Dept Organ Chem, CR-16628 Prague 6, Czech Republic
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 60期
关键词：
CALIXARENES;
D O I：
10.1039/c3cc43284j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The regioselective mercuration of tetraalkylated calix[4]arenes with Hg(OCOCF3)(2) leads to the formation of meta-substituted products which enabled Pd-catalysed intramolecular bridging within the calixarene skeleton. Bridged derivatives represent a completely novel substitution pattern in calixarene chemistry with extremely distorted cavities and possible applications in supramolecular chemistry.
引用
收藏
页码：6749 / 6751
页数：3
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