Dynamical process of exciton trapping in Fullerene

被引:0
|
作者
Zhang, GP
Zhao, H
Sun, X
George, TF
Pandey, LN
机构
[1] ACAD SINICA,NATL LAB INFRARED PHYS,SHANGHAI 200083,PEOPLES R CHINA
[2] UNIV WISCONSIN,OFF CHANCELLOR,DEPT CHEM & PHYS & ASTRON,STEVENS POINT,WI 54481
[3] WASHINGTON STATE UNIV,DEPT PHYS & CHEM,PULLMAN,WA 99164
关键词
semi-empirical models and model calculations; atomistic dynamics; fullerenes;
D O I
10.1016/S0379-6779(97)81166-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Due to the electron-lattice interaction, photoexcitation in Cco induces bond distortion, which forms a sell-trapping exciton and reduces the symmetry of C-60 from I-h to D-5d. The dynamical process of forming the self-trapping exciton is simulated by demonstrating the evolution of both bond distortion and electronic states. It is found that the relaxation time for the exciton trapping time is about 90 fs, which is four times faster than that of charge transfer in C-60.
引用
收藏
页码:2375 / 2378
页数:4
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