Non-Markovian stochastic Schrodinger equation

被引:89
|
作者
Gaspard, P
Nagaoka, M
机构
[1] Free Univ Brussels, Fac Sci, Serv Chim Phys, B-1050 Brussels, Belgium
[2] Free Univ Brussels, Fac Sci, Ctr Nonlinear Phenomena & Complex Syst, B-1050 Brussels, Belgium
[3] Nagoya Univ, Grad Sch Human Informat, Chikusa Ku, Nagoya, Aichi 4648601, Japan
[4] Inst Fundamental Chem, Sakyo Ku, Kyoto 606, Japan
来源
JOURNAL OF CHEMICAL PHYSICS | 1999年 / 111卷 / 13期
关键词
D O I
10.1063/1.479868
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report a study of a stochastic Schrodinger equation corresponding to the Redfield master equation with slipped initial conditions, which describes the dynamics of a slow subsystem weakly coupled to a fast thermal bath. Using the projection-operator method of Feshbach, we derive a non-Markovian stochastic Schrodinger equation of the generalized Langevin type, which simulates the time evolution of the quantum wave functions of the subsystem driven by the fluctuating bath. For delta-correlated baths, the non-Markovian stochastic Schrodinger equation reduces to the previously derived Markovian one. Numerical methods are proposed to simulate the time evolution under our non-Markovian stochastic Schrodinger equation. These methods are illustrated with the spin-boson model. (C) 1999 American Institute of Physics. [S0021-9606(99)50237-7].
引用
收藏
页码:5676 / 5690
页数:15
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