High-performance supercapacitor based on reduced graphene oxide decorated with europium oxide nanoparticles

被引:34
|
作者
Naderi, Hamid Reza [1 ]
Ganjali, Mohammad Reza [1 ,2 ]
Dezfuli, Amin Shiralizadeh [1 ]
机构
[1] Univ Tehran, Ctr Excellence Electrochem, Fac Chem, Tehran, Iran
[2] Univ Tehran Med Sci, Endocrinol & Metab Mol Cellular Sci Inst, Biosensor Res Ctr, Tehran, Iran
基金
美国国家科学基金会;
关键词
ELECTRODE; CARBON; TEMPERATURE;
D O I
10.1007/s10854-017-8234-2
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Many technologies benefit from the advantages induced to graphene oxide through its loading with nano-structured species. Among these areas are the rapidly growing areas of catalysis, as well as sensing and energy storage devices. The focus of this work is on the synthesis of Eu2O3 nanoparticles (EuNs) by means of a facile sonochemical procedure and anchoring them onto the surface of reduced graphene oxide (RGO), through self-assembly thereof. Further, the supercapacitive characteristics of the products were evaluated through testing electrodes made of the prepared materials. The studies were conducted through cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy and the results proved that EuNs decorated RGO (EuN-RGO) have a specific capacitance (SC) of 313 F g(-1) in a 3.0 M KCl electrolyte, at 2 mV s(-1); and also 268 F g(-1) under a current density of 2 Ag-1 based on the galvanostatic charge-discharge evaluations. The properties offered by the EuN-RGO samples could be the result of the synergy between the considerable charge mobility of the inorganic ingredient and the flexibility of the RGO sheets. The EuN-RGO further showed a high cycling durability of 96.5% of the original SC value after 4000 cycles.
引用
收藏
页码:3035 / 3044
页数:10
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