Retrograded starches as potential anodes in lithium-ion rechargeable batteries

被引：4
|
作者：
Lian Xijun [1 ,2 ,3 ]
Wen Yan [4 ]
Zhu Wei [4 ]
Li Lin [2 ,3 ]
Zhang Kunsheng [1 ]
Wang Wanyu [1 ]
机构：
[1] Tian Jin Univ Commerce, Sch Food Sci & Biotechnol, Tian Jin Key Lab Food Biotechnol, Tianjin 300134, Peoples R China
[2] S China Univ Technol, Coll Light Ind & Food Sci, Guangzhou 510640, Guangdong, Peoples R China
[3] Guangdong Prov Key Lab Green Proc Nat Prod & Prod, Guangzhou 510640, Guangdong, Peoples R China
[4] Tian Jin Univ Commerce, Sch Sci, Tianjin 300134, Peoples R China
来源：
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES | 2012年 / 51卷 / 04期
关键词：
Retrograded potato amylose and amylopectin; Crystal; Rechargeable batteries;
D O I：
10.1016/j.ijbiomac.2012.06.015
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Retrograded starch is a crystal formed by starch molecules with hydrogen bonds. Many literatures have reported its physicochemical character, but its crystal structure is so far unclear. As we isolate amylose and amylopectin from retrograded maize, sweet potato and potato starches in 4.0 M KOH solutions and make them retrograde alone in neutral solution (adjusted by HCl) to form crystal, a new phenomenon appears, crystals of KCl do not appear in retrograded potato amylose, potato amylopectin, and maize amylose, indicating that those crystals may absorb K+ and (or) Cl-, and those ions probably act with aldehyde of starch or hydroxy of fatty acid attached in starch, such characteristic may make retrograded starches replace graphite as anode with high-capacity in lithium-ion rechargeable batteries. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：632 / 634
页数：3
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