Donor-acceptor mechanism of complex formation

被引：0
|
作者：
Batsanov, SS [1 ]
机构：
[1] Ctr High Dynam Pressures, Mendeleyevsk, Moscow Oblast, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2002年 / 28卷 / 01期
关键词：
D O I：
10.1023/A:1013769217577
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The gas-phase van der Waals complexes formed in the course of donor-acceptor interaction are shown to become coordination compounds only in the crystalline state. With close lengths of the covalent-ionic and coordination bonds, their energies differ by similar to100 kJ. This energy difference is due to the work spent to overcome van der Waals forces during the formation of complex ions from interacting molecules.
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页码：1 / 5
页数：5
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