Inspired cheese-like biomass-derived carbon with plentiful heteroatoms for high performance energy storage

被引:30
|
作者
Liu, Yongchao [1 ]
Shi, Minjie [1 ]
Yan, Chao [1 ]
Zhuo, Qiqi [1 ]
Wu, Hanzhao [1 ]
Wang, Lei [1 ]
Liu, Hu [2 ,3 ,4 ]
Guo, Zhanhu [2 ]
机构
[1] Jiangsu Univ Sci & Technol, Sch Mat Sci & Engn, Zhenjiang 212003, Jiangsu, Peoples R China
[2] Univ Tennessee, Dept Chem & Biomol Engn, ICL, Knoxville, TN 37996 USA
[3] Zhengzhou Univ, Key Lab Mat Proc & Mold, Zhengzhou 450002, Henan, Peoples R China
[4] Zhengzhou Univ, Natl Engn Res Ctr Adv Polymer Proc Technol, Minist Educ, Zhengzhou 450002, Henan, Peoples R China
关键词
HIERARCHICAL POROUS CARBON; FACILE SYNTHESIS; LITHIUM; GRAPHENE; ANODES; ELECTRODE; NANOSHEETS; ARCHITECTURES; CHANNELS; NITROGEN;
D O I
10.1007/s10854-019-00965-2
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Directional construction of high performance carbon electrode from biomass plays a critical role in the development of energy storage devices. Herein, a straightforward and scalable route is reported to develop a cheese-like biomass-derived carbon electrode with plentiful heteroatoms for sodium-ion batteries and lithium-ion batteries by using egg white as a precursor. The resultant cheese-like structure provides more ion transport channels, shorter ion transport distance and increased charge transfer efficiency. At the same time, the self-doping by heteroatoms could offer high electronic conductivity and rich active sites. Benefited from the reasonable arrangement, the as-prepared electrode exhibits significantly enhanced sodium storage properties including highly reversible capacity (226.8mA h g(-1) at 100mA g(-1)), superior rate capability and excellent capacity retention (92.8%). It also shows great lithium ion capacity (567.5mA h g(-1) after 80 cycles at 100mA g(-1)), fine rate capability and outstanding capacity retention (104.8%). This work could shed light on the effective and scalable preparation of biomass-derived carbon for efficient energy storage applications.
引用
收藏
页码:6583 / 6592
页数:10
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