Thermodynamic validation of double bond comprised ionic liquids for CO2 capture

被引:14
|
作者
Wang, Yuan [1 ]
Zheng, Cailv [1 ]
Wang, Yilin [1 ]
Chen, Hanxiang [1 ]
Xu, Yun [1 ]
机构
[1] China Pharmaceut Univ, Sch Engn, Nanjing 210009, Jiangsu, Peoples R China
来源
基金
中国国家自然科学基金;
关键词
Ionic liquids; CO2; ABsorption; Thermodynamic analysis; CARBON-DIOXIDE; AQUEOUS-SOLUTIONS; SOLUBILITY; TEMPERATURE; EFFICIENT; H2S; EQUILIBRIUM; ABSORPTION; SEPARATION; GAS;
D O I
10.1016/j.jece.2018.11.019
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A new kind of ionic liquids has been synthesized which comprised double bonds in the structure of anions (DB-ILs). Their physical properties, including densities, viscosities, activation energies and diffusion coefficients were determined. Temperature-dependent Krichevsky-Kasarnovsky (K-K) was used to deal with the data of solubility of CO2 in DB-ILs, thermo-properties including solve enthalpy (Delta H-sol), entropy (Delta S-sol) and Gibbs free energy (Delta G(sol)) were obtained. The research shows that DB-ILs perform well at the capturing CO2 and can be regenerated four times.
引用
收藏
页数:6
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