SYNTHESIS AND CHARACTERIZATION OF BIS- AND TRIS-(4-CARBOXYBENZOYL)-ALKANEAMINES

被引：1

作者：

Guarda, L. ^{[1
]}

Parra, N. ^{[1
]}

Chavez, M. S. ^{[1
]}

Belmar, J. ^{[1
]}

Jimenez, C. A. ^{[1
]}

Pasan, J. ^{[2
]}

Ruiz-Perez, C. ^{[2
]}

机构：

[1] Univ Concepcion, Fac Chem Sci, Dept Organ Chem, Concepcion, Chile

[2] Univ La Laguna, Fac Fis, Dept Fis Fundamental 2, Lab Rayos & Mat Mol X, E-38204 San Cristobal la Laguna, Spain

来源：

JOURNAL OF THE CHILEAN CHEMICAL SOCIETY | 2012年 / 57卷 / 03期

关键词：

Acylating Agents; Ligands design; Amides; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; EXTENDED STRUCTURES; COMPLEXES; FRAMEWORK; NETWORK; ADSORPTION; PYRIDINE; LIGAND; AMIDE;

D O I：

10.4067/S0717-97072012000300023

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A practical and efficient protocol to obtain bis- and tris-(4-carboxybenzoyl)alkaneamines based on monoprotected 1,4-benzenedicarboxylic acid is reported here. N-(4-methoxycarbonylbenzoyloxy)succinimide was treated with aliphatic diamines and triamines to form aliphatic hydrocarbon-linked bis- and tris-amides 4a-4e. The yields ranged from good to very good and showed that choosing the right acylating agent is a key point in this synthesis. All the compounds were characterized by elemental analysis, FTIR, and H-1 NMR.

引用

页码：1305 / 1308

页数：4

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