Enhanced catalytic activity of a hierarchical porous metal-organic framework CuBTC

被引：34
|
作者：
Hu, Zhigang [1 ]
Peng, Yongwu [1 ]
Tan, Kai Min [1 ]
Zhao, Dan [1 ]
机构：
[1] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117585, Singapore
来源：
CRYSTENGCOMM | 2015年 / 17卷 / 37期
关键词：
HYDROGEN STORAGE; CU-BTC; POROSITY; SERIES; MESOPORES; SORPTION; LIGANDS; MOFS;
D O I：
10.1039/c5ce00938c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A previously reported mixed ligand strategy was used to synthesize a classic metal-organic framework CuBTC, which exhibited a hierarchical porous structure including micropores and around 3.9 nm. Thanks to the facile mass transfer and denser open metal sites induced by the mixed ligand strategy, the hierarchical porous CuBTC demonstrates enhanced catalytic activity towards both the ring-opening reaction of styrene oxide to 2-methoxy-2-phenylethanol and the cyanosilylation reaction of benzaldehyde to cyanohydrins.
引用
收藏
页码：7124 / 7129
页数：6
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