Catalytic combustion of ethyl acetate over ceria-promoted platinum supported on Al2O3 and ZrO2 catalysts

被引:6
|
作者
Pecchi, G
Reyes, P
Jiliberto, MG
López, T
Fierro, JLG
机构
[1] Univ Concepcion, Fac Ciencias Quim, Dept Fis Quim, Concepcion, Chile
[2] Univ Autonoma Metropolitana Iztapalapa, Mexico City 09340, DF, Mexico
[3] CSIC, Inst Catalisis & Petroleoquim, Madrid, Spain
关键词
platinum; ceria; zirconia; combustion; ethyl acetate;
D O I
10.1007/s10971-005-6623-0
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Platinum-supported catalysts prepared by impregnation of mixed CeO2/Al2O3 and CeO2/ZrO2 oxides using the sol-gel method were characterized and used in the combustion of ethyl acetate. In each series, the effect of CeO2 loading (3 and 5 wt%) was studied. Characterization data from the studied catalysts (specific area measurements, hydrogen chemisorption, programmed temperature reduction (TPR), X-ray diffraction (XRD), photoelectron spectra (XPS) and transmission electron microscopy (TEM)) revealed significant changes in porosity and metal dispersion in each series. The catalytic activity of the solids, evaluated in the total combustion of ethyl acetate, exhibited a positive effect with the addition of Cc in the zirconia series whereas no significant changes was observed in the alumina series.
引用
收藏
页码:169 / 174
页数:6
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