Constructing an Ion Pathway for Uranium Extraction from Seawater

被引:118
|
作者
Wang, Zeyu [1 ]
Meng, Qinghao [1 ]
Ma, Rongchen [1 ]
Wang, Zhikun [2 ]
Yang, Yajie [1 ]
Sha, Haoyan [3 ]
Ma, Xujiao [1 ]
Ruan, Xianghui [1 ]
Zou, Xiaoqin [1 ]
Yuan, Ye [1 ]
Zhu, Guangshan [1 ]
机构
[1] Northeast Normal Univ, Key Lab Polyoxometalate Sci, Minist Educ, Renmin Ave, Changchun 130024, Peoples R China
[2] China Univ Petr East China, Coll Sci, Qingdao 266580, Shandong, Peoples R China
[3] Univ Calif Davis, Dept Chem Engn, Davis, CA 95616 USA
来源
CHEM | 2020年 / 6卷 / 07期
基金
中国国家自然科学基金;
关键词
POROUS AROMATIC FRAMEWORK; EFFICIENT; SORBENTS; CAPTURE; FIBERS;
D O I
10.1016/j.chempr.2020.04.012
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Uranium extraction from seawater is a major barrier for the development of nuclear power to cope with the energy and climate-change crises. Here, we report the integration of conductive chains into porous adsorbents, which provide the expended electric field to cover the micrometer-sized adsorbent particles under alternating currents. On the basis of the superiority (large accessible area and tailorable adsorption site) of porous adsorbent for chemical adsorption, the live media promote the migration and enrichment of uranyl ions into the porous architecture. The superstructure shows 2-3 orders of magnitude faster kinetics than the polymer adsorbents under physical diffusion. Such an adsorbent enables a strong affinity that captures 99.1% of uranium in 120 min (from similar to 4.4 to similar to 0.04 ppb) It achieves the uranium extraction standard (6.0 mg g(-1)) in similar to 16 days and captures 13.0 mg g(-1) of uranium in 56 days from natural seawater.
引用
收藏
页码:1683 / 1691
页数:9
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