Chlorination of adamantane and its derivatives by carbon tetrachloride in the presence of manganese-, vanadium-, and molybdenum-containing catalysts

被引:0
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作者
Khusnutdinov, RI [1 ]
Shchadneva, NA [1 ]
Baiguzina, AR [1 ]
Lavrent'eva, YY [1 ]
Burangulova, RY [1 ]
Dzhemilev, UM [1 ]
机构
[1] Russian Acad Sci, Inst Petroleum Chem & Catalysis, Ufa Sci Ctr, Ufa, Bashkortostan, Russia
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The feasibility of catalytic chlorination of adamantane and its derivatives by carbon tetrachloride in the presence of manganese-, vanadium-, and molybdenum-containing catalysts activated by nitrile ligands or alcohols was established. The optimum molar ratios of catalyst components and reactants and the optimum reaction conditions for selective syntheses of mono-, di-, and trichlorosubstituted adamantane derivatives with high yields were found.
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页码:126 / 133
页数:8
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