Synthesis and applications to asymmetric catalysis of a series of mono- and bis(diazaphospholidine) ligands

被引：44

作者：

Smyth, D ^{[1
]}

Tye, H ^{[1
]}

Eldred, C ^{[1
]}

Alcock, NW ^{[1
]}

Wills, M ^{[1
]}

机构：

[1] Glaxo Wellcome Res & Dev Ltd, Glaxo Wellcome Med Res Ctr, Stevenage SG1 2NY, Herts, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2001年 / Royal Society of Chemistry卷 / 21期

关键词：

D O I：

10.1039/b106399p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of a series of closely related mono- and bis(diazaphospholidine) ligands has been achieved using the condensation of a diamine with a bis(dimethylamino)arylphosphine. The resulting ligands have given excellent results in palladium-catalysed allylic substitution reactions to form C-C bonds (up to 89% ee) and C-N bonds (up to 78% ee).

引用

页码：2840 / 2849

页数：10

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