Activity of commercial zeolites with iron impurities in direct N2O decomposition

被引：39
|
作者：
Oygarden, Arne H.
Perez-Ramirez, Javier
机构：
[1] ICREA, Tarragona 43007, Spain
[2] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
[3] Yara Technol Ctr Porsgrunn, N-3908 Porsgrunn, Norway
来源：
APPLIED CATALYSIS B-ENVIRONMENTAL | 2006年 / 65卷 / 1-2期
关键词：
zeolites; framework type; N2O decomposition; iron impurities; steaming;
D O I：
10.1016/j.apcatb.2006.03.002
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Various commercially available zeolite frameworks (MFI, FER, BEA, MOR, FAU) with iron impurities ranging from 85 to 780 ppm and nominal Si/Al ratios of 10-15 have been tested in direct N2O decomposition after calcination and steam treatment. Our results show a significant impact of the framework type on the catalytic activity at these high degrees of iron dilution (Fe/Al < 0.01). H-beta was the most effective material in the reaction, followed by the other pentasyl-type H-ferrierite and H-ZSM-5 zeolites. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：163 / 167
页数：5
相关论文
共 50 条
  • [1] Steam-activated FeMFI zeolites.: Evolution of iron species and activity in direct N2O decomposition
    Pérez-Ramírez, J
    Kapteijn, F
    Groen, JC
    Doménech, A
    Mul, G
    Moulijn, JA
    JOURNAL OF CATALYSIS, 2003, 214 (01) : 33 - 45
  • [2] Catalytic performance of different types of iron zeolites in N2O decomposition
    Wang Junying
    Xia Haian
    Ju Xiaohua
    Fan Fengtao
    Feng Zhaochi
    Li Can
    CHINESE JOURNAL OF CATALYSIS, 2013, 34 (05) : 876 - 888
  • [3] The surface chemistry of N2O decomposition on iron containing zeolites (I)
    Pirngruber, GD
    JOURNAL OF CATALYSIS, 2003, 219 (02) : 456 - 463
  • [4] N2O decomposition over iron modified zeolites ZSM-5
    Waclaw, A
    Nowinska, K
    Schwieger, W
    Zielinska, A
    CATALYSIS TODAY, 2004, 90 (1-2) : 21 - 25
  • [5] Direct and NO-assisted N2O decomposition over Cu-zeolites
    Smeets, P. J.
    Groothaert, M. H.
    van Teeffelen, R. M.
    Leeman, H.
    Hensen, E. J. M.
    Schoonheydt, R. A.
    FROM ZEOLITES TO POROUS MOF MATERIALS: THE 40TH ANNIVERSARY OF INTERNATIONAL ZEOLITE CONFERENCE, PROCEEDINGS OF THE 15TH INTERNATIONAL ZEOLITE CONFERENCE, 2007, 170 : 1080 - 1087
  • [6] Iron exchanged ZSM-5 and Y zeolites calcined at different temperatures: activity in N2O decomposition
    M. Rutkowska
    L. Chmielarz
    M. Jabłońska
    C. J. Van Oers
    P. Cool
    Journal of Porous Materials, 2014, 21 : 91 - 98
  • [7] Iron exchanged ZSM-5 and Y zeolites calcined at different temperatures: activity in N2O decomposition
    Rutkowska, M.
    Chmielarz, L.
    Jablonska, M.
    Van Oers, C. J.
    Cool, P.
    JOURNAL OF POROUS MATERIALS, 2014, 21 (01) : 91 - 98
  • [8] Decomposition of N2O on Rh-loaded zeolites
    Imamura, S
    Kitao, T
    Kanai, H
    Shono, S
    Utani, K
    Jindai, H
    REACTION KINETICS AND CATALYSIS LETTERS, 1997, 61 (01): : 201 - 207
  • [9] Metal exchanged zeolites for catalytic decomposition of N2O
    Labhsetwar, Nitin
    Dhakad, M.
    Biniwale, R.
    Mitsuhashi, T.
    Haneda, H.
    Reddy, P. S. S.
    Bakardjieva, S.
    Subrt, J.
    Kumar, Suresh
    Kumar, Vivek
    Saiprasad, P.
    Rayalu, S.
    CATALYSIS TODAY, 2009, 141 (1-2) : 205 - 210
  • [10] Decomposition of N2O on Rh-loaded zeolites
    S. Imamura
    T. Kitao
    H. Kanai
    S. Shono
    K. Utani
    H. Jindai
    Reaction Kinetics and Catalysis Letters, 1997, 61 : 201 - 207
12345