CO2 anion-radical in organic carboxylations

被引：43
|
作者：
Otero, MD [1 ]
Batanero, B [1 ]
Barba, F [1 ]
机构：
[1] Univ Alcala de Henares, Dept Organ Chem, E-28871 Alcala De Henares, Madrid, Spain
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 13期
关键词：
CO2; anion-radical; carboxylation; paired electrosynthesis;
D O I：
10.1016/j.tetlet.2006.01.113
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This letter shows a first approximation to the use of CO2, anion-radical in the obtention of alpha-methyl and alpha-ethylcyanoacetic acids from propionitrile and butyronitrile, respectively, through a paired electrochemical reaction with CO2. The electrosynthesis of alpha-chloro-phenylacetic acid from benzyl chloride and phenylacetic acid from toluene by another proposed pathway is also discussed. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2171 / 2173
页数：3
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