Metal-metal bonded compounds with uncommon low oxidation state

被引：40

作者：

Cao, Chun-Shuai ^{[1
,2
]}

Shi, Ying ^{[1
,2
]}

Xu, Hang ^{[1
,2
]}

Zhao, Bin ^{[1
,2
]}

机构：

[1] Nankai Univ, Dept Chem, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China

[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2018年 / 365卷

基金：

中国国家自然科学基金;

关键词：

Metal-metal bonds; Low oxidation state; Electronic structure; Syntheses and applications; ALPHA-DIIMINE LIGAND; DIMERIC MAGNESIUM(I) COMPOUND; DOUBLE-SANDWICH COMPLEX; RAY CRYSTAL-STRUCTURE; MO QUADRUPLE BONDS; STRUCTURAL-CHARACTERIZATION; ELECTRONIC-STRUCTURE; GA-GA; STABLE COMPOUND; QUINTUPLE BOND;

D O I：

10.1016/j.ccr.2018.03.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Over the past decade, the metal-metal bonded compounds with uncommon low oxidation state has tremendously facilitated the development of metal-metal bond chemistry. Herein, we review the syntheses, molecular and electronic structures, important properties and applications of more than one hundred metal-metal bonded compounds with uncommon low oxidation state. These compounds cover both homonuclear metal-metal bonded compounds and heteronuclear ones, as well various metal-metal bonds from localized bi-center to delocalized multi-center systems. Furthermore, theoretical calculations on some compounds systematically analyzed orbital bonding and electron occupancy, further elucidating the intrinsic relationship among the functions, stabilities and structures. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：122 / 144

页数：23

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