Host-guest complexation: a general strategy for electrosynthesis of conductive polymers.

被引：11
|
作者：
Bergamini, JF [1 ]
Lagrost, C [1 ]
Ching, KIC [1 ]
Jouini, M [1 ]
Lacroix, JC [1 ]
Aeiyach, S [1 ]
Lacaze, PC [1 ]
机构：
[1] Univ Paris 07, Inst Topol & Dynam Syst, CNRS, F-75005 Paris, France
来源：
SYNTHETIC METALS | 1999年 / 102卷 / 1-3期
关键词：
electropolymerization; host-guest compounds; molecular wire; polypseudorotaxanes (supramolecular electrochemistry);
D O I：
10.1016/S0379-6779(98)00526-8
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Inclusion compounds using hydroxypropyl-beta-cyclodextrin as host molecule have been used to electropolymerize some hydrophobic organic compounds in aqueous medium. This general strategy makes it possible to grow conducting polymers in aqueous medium by anodic oxidation. It is an easy method of obtaining conducting polymers in a very mild manner. Some threaded conducting molecular wire and some water-soluble and processable materials were obtained. Specific conducting polymers which seem to be encapsulated by hydroxypropyl-beta-cyclodextrin with some specific inter-chain organization were deposited on solid electrodes.
引用
收藏
页码：1538 / 1539
页数：2
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