Dielectric and ultrasonic investigation of phase transition in CuInP2S6 crystals

被引：66
|
作者：
Banys, J
Macutkevic, J
Samulionis, V
Brilingas, A
Vysochanskii, Y
机构：
[1] Vilnius State Univ, Fac Phys, LT-2040 Vilnius, Lithuania
[2] Uzhgorod State Univ, Inst Solid State Phys & Chem, UA-294000 Uzhgorod, Ukraine
来源：
PHASE TRANSITIONS | 2004年 / 77卷 / 04期
关键词：
dielectric spectroscopy; dispersion; phase transition; ionic conductivity; ultrasonic velocity; attenuation;
D O I：
10.1080/01411590410001667608
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Investigation results of dielectric and ultrasonic properties of layered CuInP2S6 crystals are presented. At low frequencies, dielectric spectra are highly influenced by the high ionic conductivity with the activation energy of 7357.4K (0.635eV). The high-frequency part of the spectra is determined by relaxational soft mode. The critical slowing down and Debye-type dispersion show the order-disorder type of the phase transition. The temperature dependence of the relaxational soft mode and dielectric contribution show a quasi-one-dimensional behaviour. Ultrasonic velocity exhibits critical slowing down which is accompanied by attenuation peaks in the phase transition region. Layered CuInP2S6 crystals have extremely large elastic nonlinearity in the direction perpendicular to layers. The nonlinear elastic parameters substantially increases at the PT temperature.
引用
收藏
页码：345 / 358
页数：14
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