Ferrocene and Pentaphosphaferrocene: A Comparative Study Regarding Redox Chemistry

被引：62
|
作者：
Butovskiy, Mikhail V. [1 ]
Balazs, Gabor [1 ]
Bodensteiner, Michael [1 ]
Peresypkina, Eugenia V. [2 ]
Virovets, Alexander V. [2 ]
Sutter, Joerg [3 ]
Scheer, Manfred [1 ]
机构：
[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany
[2] RAS, Siberian Div, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
[3] Univ Erlangen Nurnberg, Inst Anorgan Chem, D-91058 Erlangen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 10期
关键词：
density functional calculations; iron; main-group chemistry; phosphorus; redox chemistry; TRIPLE-DECKER COMPLEXES; LIGAND; IRON; RUTHENIUM; PHOSPHAFERROCENES; PHOSPHORUS; TRANSITION; P(N); P-5;
D O I：
10.1002/anie.201209329
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Pentaphosphaferrocene redox chemistry: Unprecedented dianionic and P-P coupled and monomeric products are obtained by the reduction of pentaphosphaferrocene with KH or K metal, whereas by oxidation a P-P coupled P102+ ligand coordinated to two CpFe units is obtained. The redox behavior clearly distinguishes pentaphosphaferrocene from its organometallic relative, ferrocene. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：2972 / 2976
页数：5
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