Structures and phase transitions in some Pb2B′B"O6 complex perovskite-type compounds

被引:3
|
作者
Barbur, I [1 ]
Ardelean, I [1 ]
机构
[1] Univ Babes Bolyai, Fac Phys, R-3400 Cluj Napoca, Romania
关键词
perovskites; phase transitions; B ' ion; ferroelectric; radii;
D O I
10.1080/01411590108227582
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In order to study the influence of substitutions and of the ionic radii of B' ions on structure and phase transitions, we present some physical measurements and data on Pb2B'B"O-6 (B" = W, Nb, Mo) complex perovskite compounds. By Mn and Fe substitution for Mg in Pb2MgWO6 compound a change in lattice parameters and shift of antiferroelectric transition temperature is observed. It appears that in all three series of compounds a linear dependence between ferroelectric or antiferroelectric transition temperature and B' ionic radii is observed.
引用
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页码:367 / 373
页数:7
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