Reduced Graphene Oxide-Supported TiO2 Fiber Bundles with Mesostructures as Anode Materials for Lithium-Ion Batteries

被引:18
|
作者
Zhen, Mengmeng [1 ]
Zhu, Xiaohe [1 ]
Zhang, Xiao [1 ]
Zhou, Zhen [2 ]
Liu, Lu [1 ]
机构
[1] Nankai Univ, Coll Environm Sci & Engn, Tianjin Key Lab Environm Remediat & Pollut Contro, Tianjin 300071, Peoples R China
[2] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Inst New Energy Mat Chem,Key Lab Adv Energy Mat C, Tianjin Key Lab Met & Mol Based Mat Chem,Minist E, Tianjin 300071, Peoples R China
关键词
graphene; hydrothermal synthesis; lithium; mesoporous materials; titanium; RATE-PERFORMANCE; ENERGY-STORAGE; NANOCOMPOSITES; NANOSHEETS; CONVERSION; NANOTUBES; LI4TI5O12; NANORODS; SHEETS; POWER;
D O I
10.1002/chem.201502352
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Although the synthesis of mesoporous materials is well established, the preparation of TiO2 fiber bundles with mesostructures, highly crystalline walls, and good thermal stability on the RGO nanosheets remains a challenge. Herein, a low-cost and environmentally friendly hydrothermal route for the synthesis of RGO nanosheet-supported anatase TiO2 fiber bundles with dense mesostructures is used. These mesostructured TiO2-RGO materials are used for investigation of Li-ion insertion properties, which show a reversible capacity of 235 mA hg(-1) at 200 mA g(-1) and 150 mA hg(-1) at 1000 mA g(-1) after 1000 cycles. The higher specific surface area of the new mesostructures and high conductive substrate (RGO nanosheets) result in excellent lithium storage performance, high-rate performance, and strong cycling stability of the TiO2-RGO composites.
引用
收藏
页码:14454 / 14459
页数:6
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