Squeezing C-C bonds

被引：44

作者：

Huntley, DR ^{[1
]}

Markopoulos, G

Donovan, PM

Scott, LT

Hoffmann, R

机构：

[1] Saginaw Valley State Univ, Dept Chem, University Ctr, MI 48710 USA

[2] Cornell Univ, Baker Lab, Dept Chem & Biol Chem, Ithaca, NY 14853 USA

[3] Boston Coll, Merkert Chem Ctr, Dept Chem, Chestnut Hill, MA 02467 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 46期

关键词：

D O I：

10.1002/anie.200502721

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) It's not how short you make it, it's how you make it short! A diverse collection of compounds with short C-C single bonds whose lengths range from 1.32 Å to 1.46 Å have been theoretically designed (see structure of a "spiderane"). The strategies for squeezing the C-C bonds (encapsulation, strapping back, and stiffening) allow shorter bonds than hybridization and conjugative effects alone. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7549 / 7553

页数：5

共 50 条

[1] Short C-C bonds
Markopoulos, Georgios
Levin, Mark
Hopf, Henning
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
[2] EXTREME C-C BONDS
Ritter, Stephen K.
[J]. CHEMICAL & ENGINEERING NEWS, 2009, 87 (19) : 32 - 33
[3] Asymmetric C-C bonds
[J]. Chemical & Engineering News, 2000, 78 (20)
[4] Extremely short C-C bonds
不详
[J]. CHEMICAL & ENGINEERING NEWS, 2005, 83 (34) : 38 - 38
[5] POLYMERS WITH THERMOSENSITIVE C-C BONDS
BRAUN, D
KUHN, KJ
MEID, H
HELLMANN, EH
HELLMANN, GP
[J]. JOURNAL OF POLYMER MATERIALS, 1994, 11 (03): : 197 - 205
[6] Interpolymers with conjugated C-C bonds
Vointseva, II
Gilman, LM
Valetskii, PM
[J]. VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1997, 39 (11): : 1767 - 1773
[7] Widening the road for C-C bonds
Ritter, SK
[J]. CHEMICAL & ENGINEERING NEWS, 2002, 80 (05) : 26 - 27
[8] FORMING ASYMMETRIC C-C BONDS
ENDERS, D
[J]. CHEMTECH, 1981, 11 (08) : 504 - 513
[9] Overlong C-C single bonds
Kaupp, G
Boy, J
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (1-2): : 48 - 49
[10] Widening the road for C-C bonds
Ritter, Stephen K.
[J]. Chemical and Engineering News, 2002, 80 (05): : 26 - 27

← 1 2 3 4 5 →