Progress on Laser-Induced Decomposition of Explosives Investigated by Spectroscopic Methods

被引:15
|
作者
Zhang, Wei [1 ]
Ma, Xianjie [2 ]
Shen, Ruiqi [1 ]
Wu, Lizhi [1 ]
Ye, Yinghua [1 ]
Hu, Yan [1 ]
Zhu, Peng [1 ]
机构
[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
[2] Northeast Res Inst Elect Technol, Jinzhou, Peoples R China
关键词
explosives; Photodecomposition; laser ignition; decomposition mechanism; spectroscopic methods; THERMAL-DECOMPOSITION; ENERGETIC MATERIALS; PENTAERYTHRITOL TETRANITRATE; MASS-SPECTROMETRY; UNIMOLECULAR DECOMPOSITION; CONDENSED-PHASE; ETHYL NITRATE; NITROBENZENE; PHOTODISSOCIATION; MECHANISM;
D O I
10.1080/05704928.2013.878719
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Abstract: In an effort to get detailed information and provide insight into the basic physical process and elementary chemical reaction involved in laser-induced reactions in explosives, different research methods, including laser-induced breakdown spectroscopy (LIBS), mass spectrometry (MS), Fourier transform infrared spectroscopy (FTIR), ultraviolet-visible (UV-Vis) spectroscopy, X-ray photoelectron spectroscopy (XPS), fluorescence spectroscopy, electron paramagnetic resonance (EPR) spectroscopy, etc., have been used to investigate the laser-induced photodecomposition of explosives experimentally. These kinds of experiments based on interactions of explosives with a laser might provide a unique contribution to solve the complex problem of combustion and detonation of laser ignition. The review is concerned with studies on laser-induced decomposition of typical explosives (nitrate esters, aromatic nitro compounds, and nitramines).
引用
收藏
页码:550 / 563
页数:14
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